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A critical review on in situ reduction of graphene oxide during preparation of conducting polymeric nanocomposites

机译:制备导电高分子纳米复合材料过程中原位还原氧化石墨烯的研究进展

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摘要

Graphene oxide (GO), prepared by chemical oxidation of graphite, serves as a building block for developing polymeric nanocomposites. However, their application in electrical conductivity is limited by the fact that the oxygen sites on GO trap electrons and impede charge transport. Conducting nanocomposites can be developed by reducing GO. Various strategies have been adopted to either reduce GO ex situ, before the composite preparation, or in situ during the development of the nanocomposites. The current state of research on in situ reduction of GO during the preparation of conducting polymeric nanocomposites is discussed in this review. The mechanism and the efficiency of reduction is discussed with respect to various strategies employed during the preparation of the nanocomposite, the type of polymer used, and the processing conditions employed, etc. Its overall effect on the electrical conductivity of the nanocomposites is also discussed and the future outlook in this area is presented.
机译:通过石墨的化学氧化制备的氧化石墨烯(GO)用作开发聚合物纳米复合材料的基础。但是,它们在电导率中的应用受到以下事实的限制:GO上的氧位会俘获电子并阻碍电荷传输。可以通过减少GO来开发导电纳米复合材料。已经采取了各种策略以在复合材料制备之前异位还原GO,或在纳米复合材料的开发过程中原位还原GO。在这篇综述中讨论了在制备导电聚合物纳米复合材料过程中GO原位还原的研究现状。就制备纳米复合材料时所采用的各种策略,所用聚合物的类型以及所采用的加工条件等方面,讨论了还原的机理和效率。还讨论了其对纳米复合材料电导率的总体影响,并介绍了该领域的未来前景。

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